1-Hexanol as a sustainable biofuel in DI diesel engines and its effect on combustion and emissions under the influence of injection timing and exhaust gas recirculation (EGR). Laminar Burning Velocities of C4–C7 Ethyl Esters in a Spherical Combustion Chamber: Experimental and Detailed Kinetic Modeling. 40 publications. A comprehensive chemical kinetic combustion model for the four butanol isomers. Burning velocities of 1-hexanol/air mixtures were measured at 1−10 bar and 423 K, over a range of equivalence ratios. Combustion of n-C3–C6 Linear Alcohols: An Experimental and Kinetic Modeling Study.
Jing Gong, Shuang Zhang, Yu Cheng, Zuohua Huang, Chenglong Tang, Jiaxiang Zhang. Guillaume Dayma, Fabien Halter, Fabrice Foucher, Christine Mounaim-Rousselle, and Philippe Dagaut . International Journal of Chemical Kinetics. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals.
A review of the combustion and emissions properties of advanced transportation biofuels and their impact on existing and future engines. C. Togbé, P. Dagaut, F. Halter, and F. Foucher . Use of higher alcohol biofuels in diesel engines: A review. A kinetic investigation of the catalytic oxidation of 2‐(3‐) hexanols to 2‐(3‐) hexanones over a series of titanium silicalites [TS‐1] is reported. Sodium hypochlorite is a powerful oxidizer, often used in acetic acid, so your product of reacting 2-hexanol with aqueous NaOCl would be 2-hexanone (ketone).
Another method of preparation entails hydroformylation of 1-pentene followed by hydrogenation of the resulting aldehydes.
Use the link below to share a full-text version of this article with your friends and colleagues. Anne Rodriguez, Olivier Herbinet, Frédérique Battin-Leclerc. Cis-3-Hexenal, another volatile organic compound, is also considered responsible for the freshly mowed grass flavor. Hexanol is produced industrially by the oligomerization of ethylene using triethylaluminium followed by oxidation of the alkylaluminium products. Also note that sodium chromate in the same solvent would give 2-hexanone. This material is available free of charge via the Internet at http://pubs.acs.org.
A study of the low-temperature oxidation of a long chain aldehyde: n-hexanal.
Jeffrey M. Bergthorson, Murray J. Thomson.
To better understand the combustion characteristics of 1-hexanol, new experimental data for the oxidation and combustion of 1-hexanol were obtained. Number of times cited according to CrossRef: Electroanalytical studies on green leaf volatiles for potential sensor development. Pengzhi Wang, Yachao Chang, Bo Niu, Xue Dong, Ming Jia. A. Mzé-Ahmed, K. Hadj-Ali, P. Diévart, P. Dagaut. A comparative study of n -propanol, propanal, acetone, and propane combustion in laminar flames.
Enter your email address below and we will send you your username, If the address matches an existing account you will receive an email with instructions to retrieve your username, © 2020 American Institute of Chemical Engineers, Journal of Advanced Manufacturing and Processing, Environmental Progress & Sustainable Energy, I have read and accept the Wiley Online Library Terms and Conditions of Use. Working off-campus? the Altmetric Attention Score and how the score is calculated. The Effect of Molecular Structure on Soot Emission of a Heavy-Duty Compression-Ignition Engine. Find more information about Crossref citation counts. It is used in the perfume industry.
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2-Hexanol is a secondary alochol. American Institute of Chemical Engineers 120 Wall St., 23rd floor New York, NY 10005 1-800-AIChemE (1-800-242-4363) (203) 702-7660 www.aiche.org. Kinetics of Oxidation of a Reformulated Jet Fuel (1-Hexanol/Jet A-1) in a Jet-Stirred Reactor: Experimental and Modeling Study. This method is practiced in industry to produce mixtures of isomeric C6-alcohols, which are precursors to plasticizers.[3]. Progress in Understanding Low-Temperature Organic Compound Oxidation Using a Jet-Stirred Reactor. The effect of total pressure on flame speed was determined.
Lei Zhou, N.J. Dam, M.D. Comparing the kinetic constants obtained in this study and those generated by the analysis of previously published n‐hexane oxyfunctionalization rate data allows one to conclude that in the latter case, hexanones are also produced by a direct primary oxidation of n‐hexane. Many isomeric alcohols have the formula C6H13OH.
K. Alexander Heufer, S. Mani Sarathy, Henry J. Curran, Alexander C. Davis, Charles K. Westbrook, and William J. Pitz . Roya Shahla, Casimir Togbé, Sébastien Thion, Romain Timothée, Maxence Lailliau, Fabien Halter, Christian Chauveau, Guillaume Dayma, Philippe Dagaut.
1-Hexanol is believed to be a component of the odour of freshly mown grass.
1-Hexanol has a high affinity for ADH /alcohol dehydrogenase/, similar to amyl and n-octyl alcohol, and is a potent inhibitor of ethanol oxidation. A comparative analysis on combustion and emissions of some next generation higher-alcohol/diesel blends in a direct-injection diesel engine. Elna J. K. Nilsson, Alexander A. Konnov. Find more information about Crossref citation counts.
The proposed mechanism shows good agreement with the present experimental data. The oxidation of 1-hexanol in these experimental conditions was modeled using an extended detailed chemical kinetic reaction mechanism (2977 reactions involving 600 species).
Progress in Energy and Combustion Science. Experimental and kinetic modeling study of laminar flame characteristics of higher mixed alcohols. The proposed mechanism shows good agreement with the present experimental data. Jiaxiang Zhang, Shaodong Niu, Yingjia Zhang, Chenglong Tang, Xue Jiang, Erjiang Hu, Zuohua Huang. Detailed kinetics of fossil and renewable fuel combustion. S. Mani Sarathy, Patrick Oßwald, Nils Hansen, Katharina Kohse-Höinghaus. Charles K. Westbrook, Marco Mehl, William J. Pitz, Goutham Kukkadapu, Scott Wagnon, Kuiwen Zhang.
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Reaction path analyses and sensitivity analyses were performed to interpret the results. The 2‐hexanols' oxidation is usually considered as the secondary reaction in the n‐hexane oxyfunctionalization process. Users are S. Mani Sarathy, Stijn Vranckx, Kenji Yasunaga, Marco Mehl, Patrick Oßwald, Wayne K. Metcalfe, Charles K. Westbrook, William J. Pitz, Katharina Kohse-Höinghaus, Ravi X. Fernandes, Henry J. Curran. Westbrook, M. Sjöberg, N.P. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting
A new chemical kinetic method of determining RON and MON values for single component and multicomponent mixtures of engine fuels.
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Xiaoyuan Zhang, Yuyang Li, Chuangchuang Cao, Jiabiao Zou, Yan Zhang, Wei Li, Tianyu Li, Jiuzhong Yang, Philippe Dagaut. Experimental and Detailed Kinetic Modeling Study of Isoamyl Alcohol (Isopentanol) Oxidation in a Jet-Stirred Reactor at Elevated Pressure. Information about how to use the RightsLink permission system can be found at
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